KINETIKA TRANSFORMASI FASA ENDAPAN SENYAWA KROM KARBIDA PADA KASUS TEMPER EMBRITTLEMENT STAINLESS STEEL ZERON-25 (SAF-2507)

Iskandar Aziz

Sari


ABSTRACT

Temper Embrittlement Kinetics Phase Transformation for percipitated of chrome carbide on SAF 2507 Sandvik duplex stainless designated as SAF 2507 is widely used in Indonesia for tanks, pressure vessels, pipe or even for structual materials. For high temperature application, the resistance of temper a mbrittlement of SAF 2507 is superior than other common duplex stainless steels. The temper embrittlement is basically caused by isothermal treatment in a certain range temperatures, therefore based in the metallography test and x-ray diffraction analysis the case could considered as kinetics of transformation of volume fraction formed for carbide compound phase. The research was conduced of i kinetics of phase transformation with emphasized in building the isoembrittlement curves for SAF 2507, in view of materials science consideration to be compared with that of engineering. XRF data's shown that SAF 2507 is catagorized as Fe-Cr-Ni dual phase stainless steels. The X-ray analysis for tempered embrittlement of SAF 2507 samples give prediction data for everage constant rate reaction (n) equals to about one, the activation energy below 850°C is 304 and for 850°C above is 307 k)/mol. With kinetics constants above, the I T diagram for iso-embrittlement was successfully built theoritical ly.

Keywords: kinetics phase transformation, temper embrittlement, iso-embrittlement curves, rate ofreaction.


PENDAHULUAN

Baja stainless zeron 25 (diimpor clad AB Sanndvik Steel, dengan alamat di S-81181 Sandviken, Sweden) saat ini banyak digunakan di bidang industri di Indonesia untuk penggunaan material pada tangki, bejana tekan, pipa dan bahkan jembatan. Keunggulan dari SAF 2507 ini adalah baja ini akan lebih dapat bertahan terhadap embrittlement pada temperatur tinggi dibandingkan baja duvlex lainnya. Fakta menunukkan bahwa baja duvlex megalami proses desensitasi di batas butir sebagai salah satu penyebab penggetasan temper. Penggetasan temper selalu dikaitkan dengan penurunan sifa mekanik (mechanical-properties) yang sering terjadi pada baja paduan yang dipanaskan ataupun didinginkan secara perlahan-lahan di selang temperatur 400-600°C. Peristiwa itu tentunya akan menjadi penting pada komponen yang tidak dapat mengalami pendinginan cepat untuk mencegah terjadinya penggetasan pada selang temperatur tersebut. Terjadinya penggetasan temper dapat ditinjau dari pengukuran temperatur pengalihan isothermalnya pada pengujian struktur-mikro dipandang dari kinetika transformasi fraksi fasa-fasa yang terjadi.

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Referensi


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